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Behavior of hydrophobic ionic liquids as liquid membranes on phenol removal: Experimental study and optimization

机译:疏水性离子液体作为液膜对苯酚的行为   去除:实验研究和优化

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摘要

Room temperature ionic liquids show potential as an alternative toconventional organic membrane solvents mainly due to their properties of lowvapor pressure, low volatility and they are often stable. In the present work,the technical feasibilities of room temperature ionic liquids as bulk liquidmembranes for phenol removal were investigated experimentally. Three ionicliquids with high hydrophobicity were used and their phenol removal efficiency,membrane stability and membrane loss were studied. Besides that, the effects ofseveral parameters, namely feed phase pH, feed concentration, NaOHconcentration and stirring speeds on the performance of best ionic liquidmembrane were also evaluated. Lastly, an optimization study on bulk ionicliquid membrane was conducted and the maximum phenol removal efficiency wascompared with the organic liquid membranes. The preliminary study shows thathigh phenol extraction and stripping efficiencies of 96.21% and 98.10%,respectively can be achieved by ionic liquid membrane with a low membrane losswhich offers a better choice to organic membrane solvents.
机译:室温离子液体显示出作为常规有机膜溶剂的替代物的潜力,这主要是由于其低蒸气压,低挥发性和通常稳定的特性。在目前的工作中,实验研究了室温离子液体作为脱除苯酚的本体液体膜的技术可行性。使用了三种疏水性高的离子液体,研究了其对苯酚的去除效率,膜稳定性和膜损失。除此之外,还评估了进料相pH,进料浓度,NaOH浓度和搅拌速度等多个参数对最佳离子液体膜性能的影响。最后进行了离子液体膜的优化研究,将最大的苯酚去除率与有机液膜进行了比较。初步研究表明,具有低膜损的离子液体膜可分别实现96.21%和98.10%的高苯酚萃取和汽提效率,这为有机膜溶剂提供了更好的选择。

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